๐ 10 Things to Know About AP Chemistry Graphs (Per Unit)
๐งฌ Unit 1: Atomic Structure (PES Graphs)
- The x-axis shows binding energy in eV.
- Each peak’s height represents number of electrons.
- Core electrons are tightly bound → appear to the right.
- Valence electrons appear far left on the graph.
- Area under peaks = number of electrons per subshell.
- Compare elements by peak position shifts.
- Ionization energy ≈ leftmost peak energy.
- PES data is used to confirm electron configurations.
- Nuclear charge increases → all peaks shift right.
- PES is useful for identifying unknown elements.
๐ Unit 2: Molecular & Ionic Compounds (Energy Diagrams)
- Bond length is shown on x-axis.
- Bond strength is reflected in depth of the energy well.
- Lowest point = optimal bond length.
- Steeper curves = stronger repulsion at short distances.
- Bond order affects both energy and length.
- Weaker bonds = shallower wells.
- Energy curves model interatomic forces.
- Used to compare bond strength across molecules.
- Correlates with bond dissociation energy.
- Equilibrium point balances attraction and repulsion.
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