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Formal Charge Calculation

Formal Charge Rescue Plan
๐Ÿ”ฅ Formal Charge Rescue Plan
๐Ÿ“ Formula: FC = Valence – (Lone Pairs + ½ Bonding Electrons)
✅ If all atoms have the same formal charge, compare where the charge sits. Give negative FC to the most electronegative atom.
๐Ÿงช “Zero formal charge ≠ equal stability!”

๐Ÿ”ฅ Top 3 Formal Charge Mistakes Students Make

  • Using total electrons instead of per-atom valence
  • Forgetting lone pairs
  • Putting negative FC on the wrong atom (e.g., C instead of O)

๐Ÿง  Which Lewis Structure is More Stable?

Look at these two versions of OCN⁻ — both have total FC = 0. Which is better?

Structure A FC: O = 0, C = 0, N = 0
Negative charge on C
Structure B FC: O = -1, C = 0, N = 0
Negative charge on O (more electronegative)

⚡ One Line Tip:

Always give negative FC to the atom that loves electrons the most — oxygen, not carbon!

๐Ÿง  Practice Question

What is the formal charge on N in NH₄⁺?

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